# Carbonate chemistry over a timecourse in pH drift experiments # S. Dudgeon, J. Kubler (CSU) # version: 2018-02-07 # ========================= trial sal_insitu temp_insitu ------------------------- 4 30.44 15 ========================= ID ALK pH_t0 pH_t2 pH_t6 pH_t20 pH_t24 pH_t30 t0_DIC_x_1e06 t2_DIC_x_1e06 t6_DIC_x_1e06 t20_DIC_x_1e06 t24_DIC_x_1e06 t30_DIC_x_1e06 t0_CO2_x_1e06 t2_CO2_x_1e06 t6_CO2_x_1e06 t20_CO2_x_1e06 t24_CO2_x_1e06 t30_CO2_x_1e06 t0_HCO3_x_1e06 t2_HCO3_x_1e06 t6_HCO3_x_1e06 t20_HCO3_x_1e06 t24_HCO3_x_1e06 t30_HCO3_x_1e06 t0_CO3_x_1e06 t2_CO3_x_1e06 t6_CO3_x_1e06 t20_CO3_x_1e06 t24_CO3_x_1e06 t30_CO3_x_1e06 ------------------------- SW-A-1-1 2040.41 8.00455 nd nd nd 8.56455 8.56455 1878.399189 nd nd nd 1576.656538 1576.656538 15.68930142 nd nd nd 3.131136522 3.131136522 1745.304523 nd nd nd 1264.647854 1264.647854 117.4053651 nd nd nd 308.8775476 308.8775476 SW-A-1-2 2040.41 8.00455 nd nd nd 8.66455 8.68455 1878.399189 nd nd nd 1507.452524 1493.316329 15.68930142 nd nd nd 2.264061672 2.118584104 1745.304523 nd nd nd 1151.213464 1128.010953 117.4053651 nd nd nd 353.9749991 363.1867918 SW-A-2-1 2040.41 8.00455 nd nd nd 8.71455 8.73455 1878.399189 nd nd nd 1471.986369 1457.701871 15.68930142 nd nd nd 1.915794401 1.79030548 1745.304523 nd nd nd 1092.990802 1069.534378 117.4053651 nd nd nd 377.0797724 386.3771882 SW-A-2-2 2040.41 8.00455 nd nd nd 8.67455 8.69455 1878.399189 nd nd nd 1500.39389 1486.221461 15.68930142 nd nd nd 2.190260274 2.04898139 1745.304523 nd nd nd 1139.628584 1116.363481 117.4053651 nd nd nd 358.575046 367.8089988 SW-A-3-1 2040.41 8.00455 nd nd nd 8.62455 8.66455 1878.399189 nd nd nd 1535.466056 1507.452524 15.68930142 nd nd nd 2.581592376 2.264061672 1745.304523 nd nd nd 1197.168489 1151.213464 117.4053651 nd nd nd 335.7159741 353.9749991 SW-A-3-2 2040.41 8.00455 nd nd nd 8.54455 8.55455 1878.399189 nd nd nd 1590.119773 1583.406402 15.68930142 nd nd nd 3.335800003 3.232050521 1745.304523 nd nd nd 1286.671295 1275.691753 117.4053651 nd nd nd 300.1126774 304.4825985 SW-A-4-1 2055.42 7.82355 nd nd nd 9.02355 9.02355 1956.769509 nd nd nd 1264.550384 1264.550384 25.22288629 nd nd nd 0.638692304 0.638692304 1849.534298 nd nd nd 742.2655261 742.2655261 82.01232397 nd nd nd 521.6461659 521.6461659 SW-A-4-2 2055.42 7.82355 nd nd nd 8.99355 9.00355 1956.769509 nd nd nd 1285.032303 1278.171557 25.22288629 nd nd nd 0.715119892 0.688768327 1849.534298 nd nd nd 775.6154757 764.4353732 82.01232397 nd nd nd 508.7017071 513.0474157 SW-A-5-1 2055.42 7.82355 nd nd nd 8.88355 8.88355 1956.769509 nd nd nd 1362.299265 1362.299265 25.22288629 nd nd nd 1.071372794 1.071372794 1849.534298 nd nd nd 902.0034975 902.0034975 82.01232397 nd nd nd 459.224395 459.224395 SW-A-5-2 2055.42 7.82355 nd nd nd 8.91355 8.92355 1956.769509 nd nd nd 1340.950422 1333.873249 25.22288629 nd nd nd 0.96107432 0.926642703 1849.534298 nd nd nd 867.0109457 855.4210194 82.01232397 nd nd nd 472.9784018 477.5255865 SW-A-6-1 2055.42 7.82355 nd nd nd 8.91355 8.92355 1956.769509 nd nd nd 1340.950422 1333.873249 25.22288629 nd nd nd 0.96107432 0.926642703 1849.534298 nd nd nd 867.0109457 855.4210194 82.01232397 nd nd nd 472.9784018 477.5255865 SW-A-6-2 2055.42 7.82355 nd nd nd 8.91355 8.92355 1956.769509 nd nd nd 1340.950422 1333.873249 25.22288629 nd nd nd 0.96107432 0.926642703 1849.534298 nd nd nd 867.0109457 855.4210194 82.01232397 nd nd nd 472.9784018 477.5255865 SW-A-7-1 2053.625 7.69415 nd nd nd 8.90415 8.94415 1994.11734 nd nd nd 1346.289216 1318.053725 34.84668845 nd nd nd 0.993500608 0.858335409 1896.833102 nd nd nd 877.0730061 830.8538495 62.43754939 nd nd nd 468.2227097 486.3415398 SW-A-7-2 2053.625 7.69415 nd nd nd 8.86415 8.87415 1994.11734 nd nd nd 1374.830368 1367.671886 34.84668845 nd nd nd 1.147478788 1.107104201 1896.833102 nd nd nd 923.8729964 912.1286694 62.43754939 nd nd nd 449.8098926 454.436112 SW-A-8-1 2053.625 7.69415 nd nd nd 8.95415 8.98415 1994.11734 nd nd nd 1311.053936 1290.21916 34.84668845 nd nd nd 0.827245003 0.739979731 1896.833102 nd nd nd 819.4109432 785.3937326 62.43754939 nd nd nd 490.815748 504.0854481 SW-A-8-2 2053.625 7.69415 nd nd nd 8.91415 8.92415 1994.11734 nd nd nd 1339.197847 1332.127143 34.84668845 nd nd nd 0.958026887 0.923695752 1896.833102 nd nd nd 865.4566216 853.8794343 62.43754939 nd nd nd 472.7831982 477.3240126 SW-A-9-1 2053.625 7.69415 nd nd nd 8.87415 8.90415 1994.11734 nd nd nd 1367.671886 1346.289216 34.84668845 nd nd nd 1.107104201 0.993500608 1896.833102 nd nd nd 912.1286694 877.0730061 62.43754939 nd nd nd 454.436112 468.2227097 SW-A-9-2 2053.625 7.69415 nd nd nd 8.92415 8.96415 1994.11734 nd nd nd 1332.127143 1304.080661 34.84668845 nd nd nd 0.923695752 0.797174764 1896.833102 nd nd nd 853.8794343 808.018212 62.43754939 nd nd nd 477.3240126 495.2652747 A-A-1-1 2282.26 8.01505 nd nd nd 8.75505 8.76505 2103.336024 nd nd nd 1632.975357 1625.114598 17.12565259 nd nd nd 1.889007513 1.825503615 1951.707527 nd nd nd 1183.045077 1169.904213 134.5028437 nd nd nd 448.0412722 453.3848813 A-A-1-2 2282.26 8.01505 nd nd nd 8.85505 8.85505 2103.336024 nd nd nd 1554.339288 1554.339288 17.12565259 nd nd nd 1.333797814 1.333797814 1951.707527 nd nd nd 1051.617026 1051.617026 134.5028437 nd nd nd 501.3884644 501.3884644 A-A-2-1 2282.26 8.01505 nd nd nd 8.51505 8.52505 2103.336024 nd nd nd 1815.309824 1808.106197 17.12565259 nd nd nd 4.126411625 4.000054026 1951.707527 nd nd nd 1487.099939 1475.140764 134.5028437 nd nd nd 324.0834735 328.9653785 A-A-2-2 2282.26 8.01505 nd nd nd 8.89505 8.92505 2103.336024 nd nd nd 1523.091643 1499.840656 17.12565259 nd nd nd 1.156091632 1.037065803 1951.707527 nd nd nd 999.447222 960.6693201 134.5028437 nd nd nd 522.4883295 538.1342704 A-A-3-1 2282.26 8.01505 nd nd nd 8.79505 8.83505 2103.336024 nd nd nd 1601.506117 1570.036789 17.12565259 nd nd nd 1.646186784 1.431487542 1951.707527 nd nd nd 1130.437922 1077.842192 134.5028437 nd nd nd 469.4220084 490.7631093 A-A-3-2 2282.26 8.01505 nd nd nd 8.67505 8.69505 2103.336024 nd nd nd 1695.436989 1679.917976 17.12565259 nd nd nd 2.471458238 2.312700841 1951.707527 nd nd nd 1287.421874 1261.499451 134.5028437 nd nd nd 405.5436568 416.1058245 A-A-4-1 2286.365 7.8501 nd nd nd 8.6901 8.6601 2171.853381 nd nd nd 1687.065745 1710.3141 26.28578031 nd nd nd 2.355739994 2.60138479 2048.983595 nd nd nd 1270.413098 1309.248859 96.58400509 nd nd nd 414.2969077 398.4638559 A-A-4-2 2286.365 7.8501 nd nd nd 8.7301 8.7501 2171.853381 nd nd nd 1655.804527 1640.093697 26.28578031 nd nd nd 2.060094137 1.924950064 2048.983595 nd nd nd 1218.160951 1191.892467 96.58400509 nd nd nd 435.5834825 446.2762799 A-A-5-1 2286.365 7.8501 nd nd nd 8.6701 8.7101 2171.853381 nd nd nd 1702.587026 1671.466767 26.28578031 nd nd nd 2.517112161 2.203548652 2048.983595 nd nd nd 1296.343742 1244.343407 96.58400509 nd nd nd 403.7261725 424.9198116 A-A-5-2 2286.365 7.8501 nd nd nd 8.8401 8.8601 2171.853381 nd nd nd 1569.193384 1553.48191 26.28578031 nd nd nd 1.409041949 1.312711377 2048.983595 nd nd nd 1073.350419 1047.096858 96.58400509 nd nd nd 494.4339225 505.0723405 A-A-6-1 2286.365 7.8501 nd nd nd 8.7801 8.8301 2171.853381 nd nd nd 1616.468851 1577.062561 26.28578031 nd nd nd 1.736924872 1.459531027 2048.983595 nd nd nd 1152.387772 1086.503024 96.58400509 nd nd nd 462.3441539 489.1000064 A-A-6-2 2286.365 7.8501 nd nd nd 8.6301 8.6401 2171.853381 nd nd nd 1733.34032 1725.692443 26.28578031 nd nd nd 2.869267269 2.777400951 2048.983595 nd nd nd 1347.685674 1334.922912 96.58400509 nd nd nd 382.7853789 387.99213 A-A-7-1 2278.565 7.68895 nd nd nd 8.66895 8.66895 2217.604332 nd nd nd 1697.161882 1697.161882 39.22521208 nd nd nd 2.517313079 2.517313079 2109.75929 nd nd nd 1293.018801 1293.018801 68.61982988 nd nd nd 401.6257678 401.6257678 A-A-7-2 2278.565 7.68895 nd nd nd 8.74895 8.79895 2217.604332 nd nd nd 1634.858336 1595.58037 39.22521208 nd nd nd 1.925272466 1.621161947 2109.75929 nd nd nd 1188.939641 1123.295473 68.61982988 nd nd nd 443.9934225 470.6637358 A-A-8-1 2278.565 7.68895 nd nd nd 8.76895 8.70895 2217.604332 nd nd nd 1619.159856 1666.137492 39.22521208 nd nd nd 1.798047705 2.20382081 2109.75929 nd nd nd 1162.703065 1241.206059 68.61982988 nd nd nd 454.6587427 422.7276119 A-A-8-2 2278.565 7.68895 nd nd nd 8.61895 8.65895 2217.604332 nd nd nd 1735.411392 1704.864733 39.22521208 nd nd nd 2.963866431 2.601564195 2109.75929 nd nd nd 1356.832493 1305.876643 68.61982988 nd nd nd 375.6150322 396.3865259 A-A-9-1 2278.565 7.68895 nd nd nd 8.66895 8.67895 2217.604332 nd nd nd 1697.161882 1689.435971 39.22521208 nd nd nd 2.517313079 2.435470909 2109.75929 nd nd nd 1293.018801 1280.11962 68.61982988 nd nd nd 401.6257678 406.8808808 A-A-9-2 2278.565 7.68895 nd nd nd 8.67895 8.67895 2217.604332 nd nd nd 1689.435971 1689.435971 39.22521208 nd nd nd 2.435470909 2.435470909 2109.75929 nd nd nd 1280.11962 1280.11962 68.61982988 nd nd nd 406.8808808 406.8808808 E-A-1-1 2466.165 8.08415 nd nd nd 8.25415 8.21415 2244.620936 nd nd nd 2151.149497 2174.824128 15.43592887 nd nd nd 9.678660294 10.82576845 2062.530484 nd nd nd 1912.858541 1951.310319 166.6545231 nd nd nd 228.6122951 212.6880406 E-A-1-2 2466.165 8.08415 nd nd nd 8.23415 8.10415 2244.620936 nd nd nd 2163.118706 2234.573499 15.43592887 nd nd nd 10.23799137 14.62855335 2062.530484 nd nd nd 1932.334761 2046.769738 166.6545231 nd nd nd 220.5459543 173.1752074 E-A-2-1 2466.165 8.08415 nd nd nd 8.37415 8.29415 2244.620936 nd nd nd 2073.817681 2126.418427 15.43592887 nd nd nd 6.853710693 8.640390685 2062.530484 nd nd nd 1785.637819 1872.410153 166.6545231 nd nd nd 281.3261512 245.3678834 E-A-2-2 2466.165 8.08415 nd nd nd 8.29415 8.20415 2244.620936 nd nd nd 2126.418427 2180.578262 15.43592887 nd nd nd 8.640390685 11.13073042 2062.530484 nd nd nd 1872.410153 1960.610265 166.6545231 nd nd nd 245.3678834 208.8372671 E-A-3-1 2466.165 8.08415 nd nd nd 8.29415 8.19415 2244.620936 nd nd nd 2126.418427 2186.266944 15.43592887 nd nd nd 8.640390685 11.44329871 2062.530484 nd nd nd 1872.410153 1969.785073 166.6545231 nd nd nd 245.3678834 205.0385732 E-A-3-2 2466.165 8.08415 nd nd nd 8.37415 8.29415 2244.620936 nd nd nd 2073.817681 2126.418427 15.43592887 nd nd nd 6.853710693 8.640390685 2062.530484 nd nd nd 1785.637819 1872.410153 166.6545231 nd nd nd 281.3261512 245.3678834 E-A-4-1 2468.805 7.8742 nd nd nd 7.8442 7.3742 2339.329721 nd nd nd 2350.801262 2506.705738 26.73402033 nd nd nd 28.85326974 91.2619227 2202.83456 nd nd nd 2218.77183 2377.974656 109.7611404 nd nd nd 103.1761629 37.46915946 E-A-4-2 2468.805 7.8742 nd nd nd 8.1342 7.8442 2339.329721 nd nd nd 2221.467162 2350.801262 26.73402033 nd nd nd 13.50147097 28.85326974 2202.83456 nd nd nd 2024.411027 2218.77183 109.7611404 nd nd nd 183.5546637 103.1761629 E-A-5-1 2468.805 7.8742 nd nd nd 8.0042 7.7342 2339.329721 nd nd nd 2284.945936 2390.151465 26.73402033 nd nd nd 19.10119712 38.03133993 2202.83456 nd nd nd 2123.137855 2270.174464 109.7611404 nd nd nd 142.7068838 81.94566112 E-A-5-2 2468.805 7.8742 nd nd nd 8.2942 8.1442 2339.329721 nd nd nd 2128.762366 2216.159914 26.73402033 nd nd nd 8.648808276 13.13914774 2202.83456 nd nd nd 1874.450073 2015.973428 109.7611404 nd nd nd 245.6634839 187.0473384 E-A-6-1 2468.805 7.8742 nd nd nd 7.7642 6.9042 2339.329721 nd nd nd 2379.791532 2726.482004 26.73402033 nd nd nd 35.29001768 276.0641281 2202.83456 nd nd nd 2257.197099 2437.40437 109.7611404 nd nd nd 87.30441619 13.01350594 E-A-6-2 2468.805 7.8742 nd nd nd 8.2742 8.1742 2339.329721 nd nd nd 2141.271016 2199.855823 26.73402033 nd nd nd 9.155429495 12.10368221 2202.83456 nd nd nd 1894.943781 1989.917723 109.7611404 nd nd nd 237.1718052 197.8344177 E-A-7-1 2470.215 7.70695 nd nd nd 7.58695 6.96695 2400.751405 nd nd nd 2439.731741 2687.537674 40.71661853 nd nd nd 54.67682796 238.5843515 2282.649919 nd nd nd 2325.256777 2433.938289 77.38486686 nd nd nd 59.79813619 15.01503303 E-A-7-2 2470.215 7.70695 nd nd nd 7.94695 7.46695 2400.751405 nd nd nd 2311.251974 2477.798849 40.71661853 nd nd nd 22.18858568 73.11388581 2282.649919 nd nd nd 2161.708988 2358.671577 77.38486686 nd nd nd 127.3544009 46.01338703 E-A-8-1 2470.215 7.70695 nd nd nd 8.32695 8.07695 2400.751405 nd nd nd 2108.970805 2251.977796 40.71661853 nd nd nd 7.877143467 15.76283642 2282.649919 nd nd nd 1840.926133 2071.581272 77.38486686 nd nd nd 260.1675289 164.6336873 E-A-8-2 2470.215 7.70695 nd nd nd 7.76695 7.12695 2400.751405 nd nd nd 2380.208688 2603.554044 40.71661853 nd nd nd 35.06852071 163.9800328 2282.649919 nd nd nd 2257.278026 2418.012693 77.38486686 nd nd nd 87.86214125 21.56131803 E-A-9-1 2470.215 7.70695 nd nd nd 8.17695 7.92695 2400.751405 nd nd nd 2199.631875 2319.587399 40.71661853 nd nd nd 12.01960927 23.36546958 2282.649919 nd nd nd 1988.648182 2173.912807 77.38486686 nd nd nd 198.964084 122.3091224 E-A-9-2 2470.215 7.70695 nd nd nd 8.07695 8.74695 2400.751405 nd nd nd 2251.977796 1787.393501 40.71661853 nd nd nd 15.76283642 2.117249956 2282.649919 nd nd nd 2071.581272 1301.486717 77.38486686 nd nd nd 164.6336873 483.7895342 SW-NA-380-1 2040.18 8.0068 nd nd nd 7.7268 7.6768 1877.300475 nd nd nd 1971.428044 1985.781497 15.59470881 nd nd nd 31.91758005 36.13395762 1743.792789 nd nd nd 1873.042206 1889.875254 117.9129776 nd nd nd 66.46825738 59.77228623 SW-NA-380-2 2040.64 8.0023 nd nd nd 7.7123 7.6723 1879.495662 nd nd nd 1976.094959 1987.505269 15.78441479 nd nd nd 33.09778973 36.54641696 1746.811702 nd nd nd 1878.52336 1891.744205 116.8995452 nd nd nd 64.47380913 59.21464656 SW-NA-620-1 2054.57 7.8234 nd nd nd 7.9034 7.8734 1955.99151 nd nd nd 1929.272111 1939.562788 25.22182028 nd nd nd 20.56237417 22.20777405 1848.817462 nd nd nd 1812.136321 1826.512453 81.95222769 nd nd nd 96.57341613 90.84256049 SW-NA-620-2 2056.27 7.8237 nd nd nd 7.8637 7.8237 1957.547471 nd nd nd 1944.462105 1957.547471 25.22394771 nd nd nd 22.78440895 25.22394771 1850.251074 nd nd nd 1832.548066 1850.251074 82.07244925 nd nd nd 89.12963 82.07244925 SW-NA-940-1 2052.64 7.6966 nd nd nd 7.7966 7.7866 1992.442453 nd nd nd 1962.578136 1965.680487 34.61882751 nd nd nd 26.96307987 27.65073153 1895.090534 nd nd nd 1858.177109 1862.191041 62.73309167 nd nd nd 77.43794773 75.83871436 SW-NA-940-2 2054.61 7.6917 nd nd nd 7.7617 7.7417 1995.791616 nd nd nd 1975.21225 1981.206467 35.07595946 nd nd nd 29.4632741 30.97454304 1898.572416 nd nd nd 1873.693773 1881.146052 62.1432405 nd nd nd 72.05520243 69.08587216 A-NA-380-1 2282.26 8.0147 nd nd nd 8.1247 8.1047 2103.486595 nd nd nd 2052.880329 2062.588696 17.14145728 nd nd nd 12.77389912 13.48435936 1951.934985 nd nd nd 1873.877037 1889.069454 134.4101535 nd nd nd 166.2293928 160.0348823 A-NA-380-2 2282.26 8.0154 nd nd nd 8.1154 8.0854 2103.185388 nd nd nd 2057.423716 2071.738235 17.1098611 nd nd nd 13.09998176 14.20333371 1951.47994 nd nd nd 1880.997846 1903.302852 134.5955869 nd nd nd 163.3258877 154.2320487 A-NA-620-1 2285.63 7.8501 nd nd nd 7.9201 7.9101 2171.141425 nd nd nd 2145.202409 2149.031969 26.27716357 nd nd nd 21.96701041 22.5400881 2048.311918 nd nd nd 2011.817415 2017.312672 96.55234387 nd nd nd 111.4179831 109.1792095 A-NA-620-2 2287.1 7.8501 nd nd nd 7.9301 7.9101 2172.565336 nd nd nd 2142.738225 2150.445002 26.29439706 nd nd nd 21.42139882 22.55490867 2049.655273 nd nd nd 2007.545672 2018.639097 96.6156663 nd nd nd 113.7711541 109.2509971 A-NA-940-1 2280.05 7.6861 nd nd nd 7.7761 7.7661 2219.954298 nd nd nd 2191.147536 2194.449647 39.52870595 nd nd nd 31.59483838 32.39640661 2112.176491 nd nd nd 2076.986844 2081.203026 68.24910079 nd nd nd 82.56585352 80.85021474 A-NA-940-2 2277.08 7.6918 nd nd nd 7.7818 7.7618 2215.25373 nd nd nd 2186.351834 2192.953614 38.92391229 nd nd nd 31.10498827 32.70352185 2107.337487 nd nd nd 2071.799144 2080.23372 68.99233155 nd nd nd 83.44770141 80.01637287 E-NA-380-1 2466.33 8.0835 nd nd nd 8.2035 8.1935 2245.098021 nd nd nd 2181.101316 2186.786046 15.4638924 nd nd nd 11.15158796 11.46467779 2063.17671 nd nd nd 1961.346487 1970.513711 166.4574188 nd nd nd 208.6032407 204.8076574 E-NA-380-2 2466 8.0848 nd nd nd 8.2148 8.1948 2244.143631 nd nd nd 2174.296872 2185.747606 15.40801105 nd nd nd 10.8054549 11.42195527 2061.883811 nd nd nd 1950.566057 1969.055977 166.8518084 nd nd nd 212.9253607 205.2696736 E-NA-620-1 2468.69 7.8737 nd nd nd 7.9937 7.9537 2339.41283 nd nd nd 2289.541991 2306.937682 26.76686031 nd nd nd 19.63327283 21.79002642 2203.002753 nd nd nd 2130.150602 2156.132095 109.6432169 nd nd nd 139.7581162 129.0155605 E-NA-620-2 2468.92 7.8747 nd nd nd 7.9847 7.9347 2339.246493 nd nd nd 2293.747059 2315.13945 26.70121724 nd nd nd 20.1027562 22.89054407 2202.666099 nd nd nd 2136.353975 2168.07211 109.8791767 nd nd nd 137.2903279 124.1767965 E-NA-940-1 2474.32 7.7056 nd nd nd 7.8256 7.8056 2405.247331 nd nd nd 2363.096902 2370.429987 40.92180388 nd nd nd 30.31285793 31.88109969 2287.032715 nd nd nd 2233.286761 2243.111701 77.29281173 nd nd nd 99.49728279 95.43718697 E-NA-940-2 2466.11 7.7083 nd nd nd 7.8183 7.7883 2396.256289 nd nd nd 2357.8063 2368.651283 40.51231445 nd nd nd 30.77257862 33.18585251 2278.267225 nd nd nd 2229.366636 2243.729955 77.47674945 nd nd nd 97.66708516 91.73547525